Spectrumhydrogen

Each atom will have its own characteristic line spektrum. At the line spectrum of hydrogen in class and saw three lines.  These red, green, and blue lines represented emissions from different energy levels in the atom.

 

Spectrum of Hydrogen

We can look at either absorption or emission spectra.

 

Using the equation for the energy of the hydrogen levels we can write an equation for the change in energy of an electron that charges orbitals and emits or absorbs a photon.

With this equation we can calculate the frequency of light emitted or absorbed when an electron moves between orbitals of different principal quantum numbers.



Using the equation above we can calculate the wavelengths for various transitions in the H-atom.



The energy required to promote an electron to n = is called the ionization energy.
(Because this is the energy required to make an ion).

A characteristic pattern of spectral lines, either absorption or emission, produced by the hydrogen atom. The various series of lines are named according to the lowest energy level involved in the transitions that give rise to the lines.



The Lyman series involve jumps to or from the ground state (n=1); the Balme series (in which all the lines are in the visible region) corresponds to n=2, the Paschen series to n=3, the Brackett series to n=4, and the Pfund series to n=5.

To illustrate with specific values, consider the Balmer series, in which the four principal lines, designated as H-alpha, H-beta, H-gamma, and H-delta, involve energy jumps of 3.02 x 10-19, 4.07 x 10-19, 4.57 x 10-19, and 4.84 x -19 joules (J), respectively, and corresponding photons of wavelengths are 656.3, 486.1, 434.0, and 410.2 nanometers (nm).

 

energy transitions in the hydrogen atom